Publications

Brigham Young University Faculty Research, Professor Rank

22. “Collision Cross-section Measurements of Collision-induced Dissociation Precursor and Product Ions in an FTICR-MS and an IM-MS: A Comparative Study,” Arslanian, Andrew J.; Mismash, Noah; Dearden, David V. J. Am. Soc. Mass Spectrom. 2022, 33 (9), 1626-1635. DOI: 10.1021/jasms.2c00089. DOI: 10.1021/jasms.2c00089.

21. “Prototypical Allosterism in a Simple Ditopic Ligand: Gas Phase Topologies of Cucurbit[n]uril•n- Alkylammonium Complexes Controlled by Binding in the Second Site,” Shrestha, Jamir; Porter, Savannah R.; Tinsley, Caleb; Arslanian, Andrew J.; Dearden, David V. J. Phys. Chem. A 2022, 126, 2950-2958. DOI: 10.1021/acs.jpca.2c01703.

20. “Multi-CRAFTI: Relative Collision Cross Sections from Fourier Transform Ion Cyclotron Resonance Mass Spectrometric Line Width Measurements,” Pope, Brigham L.; Joaquin, Daniel; Hickey, Jacob T.; Mismash, Noah; Heravi, Tina; Shrestha, Jamir; Arslanian, Andrew J.; Anupriya; Mortensen, Daniel N.; Dearden, David V. J. Am. Soc. Mass Spectrom. 2022, 33, 131- 140. DOI: 10.1021/jasms.1c00297.

19. “Halide Size-Selective Binding by Cucurbit[5]uril-Alkali Cation Complexes in the Gas Phase,” Heravi, Tina; Shen, Jiewen; Johnson, Spencer; Asplund, Matthew C.; Dearden, David V. J. Phys. Chem. A, 2021, 125, 7803-7812. DOI: 10.1021/acs.jpca.1c05060.

18. “Quantitative Collision Cross-Sections from FTICR Linewidth Measurments: Improvements in Theory and Experiment,” Anupriya; Gustafson, E.; Mortensen, D. N.; Dearden, D. V. J. Am. Soc. Mass Spectrom. 2018, 29, 251-259. doi: 10.1007/s13361-017-1738-4.

17. "Quantitative Collision Cross-Sections from FTICR Linewidth Measurments: Improvements in Theory and Experiment," Anupriya; Gustafson, E.; Mortensen, D. N.; Dearden, D. V. J. Am. Soc. Mass Spectrom. 2017, in press. doi: 10.1007/s13361-017-1738-4.

16. "Collision Cross Sections for 20 Protonated Amino Acids: Fourier Transform Ion Cyclotron Resonance and Ion Mobility Results." Anupriya; Jones, C. A.; Dearden, D. V. J. Am. Soc. Mass Spectrom. 2016, 27, 1366-1375. doi: 10.1007/s13361-016-1409-x.

15. "Linewidth Pressure Measurement: a New Technique for High Vacuum Characterization," Jones, C. A.; Dearden, D. V. J. Am. Soc. Mass Spectrom. 2015, 26, 323-329. doi:10.1007/s13361-014-1031-8.

14. "Effects of Kinetic Energy and Collision Gas in Measurement of Cross Sectional Areas by Fourier Transform Ion Cyclotron Resonance," Yang, F.; Dearden, D. V. Int. J. Mass Spectrom. 2015, 378, 143-150. doi:10.1016/j.ijms.2014.07.026.

13. "Binding of α,ω-Alkyldiammonium Ions by Cucurbit[n]urils in the Gas Phase," Yang, F.; Jones, C. A.; Selvapalam, N.; Ko, Y. H.; Kim, K.; Dearden, D. V. Supramol. Chem. 2014, 26, 684-691.

12. "Cavitands with chiral substituents: resorcinarene-based cavitands with amino functional groups," Li, N.; Yang, F.; Stock, H. A.; Dearden, D. V.; Lamb, J. D.; Harrison, R. G. Org. Biomol. Chem. 2012, 10, 7382-7401.

11. “Collision Cross Sectional Areas from Analysis of Fourier Transform Ion Cyclotron Resonance Line Width: a New Method for Characterizing Molecular Structure,” Yang, F.; Voelkel, J. E.; Dearden, D. V. Anal. Chem. 2012, 84, 4851-4857.

10. “Appropriate Choice of Event Length in Sustained Off-Resonance Irradiation Collision Induced Dissociation (SORI-CID) Experiments: Activated Ion Collision-induced Dissociation,” Mortensen, D. N.; Jones, C. A.; Dearden, D. V. Int. J. Mass Spectrom. 2012, 330-332, 241-245.

9. “Gas Phase Cucurbit[n]uril Chemistry,” Yang, F.; Dearden, D. V. Isr. J. Chem. 2011, 51, 551-558.

8. “Influence of charge repulsion on binding strengths: experimental and computational characterization of mixed alkali metal complexes of decamethylcucurbit[5]uril,” Mortensen, D. N.; Dearden, D. V. Chem. Commun. 2011, 47, 6081-6083.

7. “Guanidinium-Capped Cucurbit[7]uril Molecular Cages in the Gas Phase,” Yang, Fan; Dearden, David V. Supramol. Chem. 2011, 23, 53-58.

6. “Equilibrium Methods for Characterizing Gas Phase Chiral Recognition,” Dearden, David. V.; Fang, Nannan. In Chiral Recognition in the Gas Phase, Zehnacker, Anne, ed.; CRC Press: Boca Raton, FL; 2010; pp. 133-142.

5. “Supramolecular Modification of Ion Chemistry: Modulation of Peptide Charge State and Dissociation Behavior through Complexation with Cucurbit[n]uril (n = 5,6) or αCyclodextrin,” Zhang, H.; Grabenauer, M.; Bowers, M. T.; Dearden, D. V. J. Phys. Chem. A 2009, 113, 1508-1517.

4. “One Ring to Bind Them All: Shape-Selective Complexation of Phenylenediamine Isomers with Cucurbit[6]uril in the Gas Phase,” Dearden, D. V.; Ferrell, T. A.; Asplund, M. C.; Zilch, L. W.; Julian, R. R.; Jarrold, M. F. J. Phys. Chem. A 2009, 113, 989-997.

3. “Molecular Beads on a Charged Molecular String: α,ω-Alkyldiammonium Complexes of Cucurbit[6]uril in the Gas Phase,” Zhang, H.; Ferrell, T. A.; Asplund, M. C.; Dearden, D. V. Int. J. Mass Spectrom. 2007, 265, 187-196.

2. “Sonic Spray Ionization Mass Spectrometry: A Powerful Tool Used to Characterize Fragile Metal-Assembled Cages,” Gardner, J. S.; Harrison, R. G.; Lamb, J. D.; Dearden, D. V. New J. Chem. 2006, 30, 1276-1282.

1. “Isotopic Compositions and Exact Masses of Single Isotopic Peaks,” Rockwood, A. L.; Van Orman, J. R.; Dearden, D. V. J. Am. Soc. Mass Spectrom. 2004, 15, 12-21.

Brigham Young University Faculty Research, Associate Professor Rank

17. “Incorporation of a Venturi Device in Electrospray Ionization,” Zhou, L.; Yue, B.; Dearden, D. V.; Lee, E. D.; Rockwood, A. L.; Lee, M. L. Anal. Chem. 2003, 75, 5978-5983.

16. “Cucurbit[6]uril Pseudorotaxanes: Distinctive Gas Phase Dissociation and Reactivity,” Zhang, H.; Paulsen, E. S.; Walker, K. A.; Krakowiak, K. E.; Dearden, D. V. J. Am. Chem. Soc. 2003, 125, 9284-9285.

15. “Host-Guest Chemistry in the Gas Phase,” Dearden, D. V. In The Encyclopedia of Mass Spectrometry; P. B. Armentrout, Ed.; Elsevier: San Diego, 2003; Vol. 1 (Theory and Ion Chemistry); pp. 763-770.

14. “Low-pressure Ion-Molecule Equilibrium,” Kellersberger, K. A.; Dearden, D. V. In The Encyclopedia of Mass Spectrometry; P. B. Armentrout, Ed.; Elsevier: San Diego, 2003; Vol. 1 (Theory and Ion Chemistry); pp. 338-345.

13. “Alkali Metal Ion Chemistry,” Anderson, J. D.; Dearden, D. V. In The Encyclopedia of Mass Spectrometry; P. B. Armentrout, Ed.; Elsevier: San Diego, 2003; Vol. 1 (Theory and Ion Chemistry); pp. 783-787.

12. “Alkali Metal Binding Energies of Dibenzo-18-crown-6: Experimental and Computational Results,” Anderson, J. D.; Paulsen, E. S.; Dearden, D. V. Int. J. Mass Spectrom. 2003, 227, 63-76.

11. “The Thermodynamic Basis for Enantiodiscrimination: Gas Phase Measurement of the Enthalpy and Entropy of Chiral Amine Recognition by Dimethyldiketopyridino-18-crown 6,” Liang, Y.; Bradshaw, J. S.; Dearden, D. V. J. Phys. Chem. A 2002, 106, 9665-9671.

10. “Encapsulation of N2, O2, Methanol, or Acetonitrile by Decamethylcucurbit[5]uril(NH4+)2 Complexes in the Gas Phase: Influence of the Guest on ‘Lid’ Tightness,” Kellersberger, K. A.; Anderson, J. D.; Ward, S. M.; Krakowiak, K. E.; Dearden, D. V. J. Am. Chem. Soc. 2001, 123, 11316-11317.

9. “Study of Gas Phase Molecular Recognition Using Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FTICR/MS),” Dearden, D. V.; Liang, Y.; Nicoll, J. B.; Kellersberger, K. A. J. Mass Spectrom. 2001, 36, 989-997.

8. “Reactions of Multidentate Ligands with Ligated Alkali Cation Complexes: Self-Exchange and ‘Sandwich’ Complex Formation Kinetics of Gas Phase Crown Ether—Alkali Cation Complexes,” Nicoll, J. B.; Dearden, D. V. Int. J. Mass Spectrom. 2001, 204, 171-183.

7. “Fundamental Factors Controlling the Exchange of Multidentate Ligands: Displacement of 12-Crown-4 and Triglyme from Complexes with Divalent Alkaline Earth Cations,” Shen, N.; Pope, R. M.; Dearden, D. V. Int. J. Mass Spectrom. 2000, 195-196, 639-652.

6. “Gas Phase Studies of Ammonium—Cyclodextrin Compounds Using Fourier Transform Ion Cyclotron Resonance,” Kellersberger, K. A.; Dejsupa, C.; Liang, Y.; Pope, R. M.; Dearden, D. V. Int. J. Mass Spectrom., 1999, 193, 181-195.

5. “Analysis of Enantiomeric Excess Using Mass Spectrometry: Fast Atom Bombardment / Sector and Electrospray Ionization / Fourier Transform Mass Spectrometric Approaches,” Liang, Y.; Bradshaw, J. S.; Izatt, R. M.; Pope, R. M.; Dearden, D. V. Int. J. Mass Spectrom. 1999, 185/186/187, 977-988.

4. “Gas Phase Stripping of Alkali Cations from Biomolecules via Reaction with Crown Ethers.” Pope, R. M.; Shen, N.; Hofstadler, S. A.; Dearden, D. V. Int. J. Mass Spectrom. 1998, 175, 179-186.

3. “Relative Ammonium Affinities of 18-Crown-6 and the Isomers of Dicyclohexano-18-Crown-6,” Dearden, D. V.; Chu, I.-H. J. Inclusion Phenom. Mol. Recognit. Chem. 1997, 29, 269-282.

2. “Intrinsic Contributions to Chiral Recognition: Discrimination Between Enantiomeric Amines by Dimethyldiketopyridino-18-crown-6 in the Gas Phase,” Dearden, D. V.; Dejsupa, C.; Liang, Y.; Bradshaw, J. S.; Izatt, R. M. J. Am. Chem. Soc. 1997, 119, 353-359.

1. “Gas Phase Salt Clusters from Electrosprayed Alkaline Earth Colloids,” Pope, R. M.; Shen, N.; Nicoll, J.; Dejsupa, C.; Dearden, D. V. Int. J. Mass Spectrom. Ion Proc. 1997, 162, 107-119.

University of Texas at Arlington and Brigham Young University Faculty Research, Assistant Professor Rank

11. “Host-Guest Molecular Recognition without Solvents.” Dearden, D. V. in Physical Supramolecular Chemistry, NATO Advanced Research Workshop Series, Echegoyen, L.; Kaifer, A., eds.; Kluwer: Dordrecht, 1996; pp. 229-247.

10. “The Macrobicyclic Cryptate Effect in the Gas Phase,” Chen, Q.; Cannell, K.; Nicoll, J.; Dearden, D. V. J. Am. Chem. Soc. 1996, 118, 6335-6344.

9. “Complexes of p-tert-butylcalix[4]arene with Mono- and Dipositive Cations in the Gas Phase,” Wong, P. S. H.; Yu, X.; Dearden, D. V. Inorg. Chim. Acta 1996, 246, 1-7.

8. “Mass Spectrometry,” Brodbelt, J. S.; Dearden, D. V. In Physical Methods in Supramolecular Chemistry; J. E. D. Davies, Ed.; Pergamon: Oxford, 1996; Vol. 8.; pp. 567-591.

7. “Effects of Alkyl Substitution on the Multidentate Attachment of Alkali Metal Cations by Ligands in the Gas Phase: Kinetics and Thermochemistry of Cation Binding by Isomers of Dicyclohexano-18-crown-6.” Chu, I.-H.; Dearden, D. V. J. Am. Chem. Soc. 1995, 117, 8197-8203.

6. “Gas Phase Studies of Valinomycin-Alkali Metal Cation Complexes: Attachment Rates and Cation Affinities.” Wong, P. S. H.; Antonio, B. J.; Dearden, D. V. J. Am. Soc. Mass Spectrom. 1994, 5, 632-637.

5. “Macrocyclic Chemistry in the Gas Phase: Intrinsic Cation Affinities and Complexation Rates for Alkali Metal Cation Complexes of Crown Ethers and Glymes.” Chu, I.-H.; Zhang, H.; Dearden, D. V. J. Am. Chem. Soc. 1993, 115, 5736-5744.

4. “Chiral Host-Guest Recognition in an Ion-Molecule Reaction.” Chu, I.-H.; Dearden, D. V.; Bradshaw, J. S.; Huszthy, P.; Izatt, R. M. J. Am. Chem. Soc. 1993, 115, 4318-4320.

3. “Macrocyclic Chemistry Without Solvents: Gas Phase Reaction Rates.” Dearden, D. V.; Zhang, H.; Chu, I.-H.; Wong, P.; Chen, Q. Pure App. Chem. 1993, 65, 423-428.

2. “The Gas-Phase Macrocyclic Effect: Reaction Rates for Crown Ethers and the Corresponding Glymes with Alkali Metal Cations.” Zhang, H.; Dearden, D. V. J. Am. Chem. Soc. 1992, 114, 2754-2755.

1. “Gas-Phase Molecular Recognition: Gas-Phase Crown Ether-Alkali Metal Ion Complexes and Their Reactions With Neutral Crowns.” Zhang, H.; Chu, I.-H.; Leming, S.; Dearden, D. V. J. Am. Chem. Soc. 1991, 113, 7415-7417.

Postdoctoral Research

5. “Detection and Characterization of Gas-Phase InCl Using Resonance Enhanced Multiphoton Ionization.” Johnson, R. D., III; Dearden, D. V.; Hudgens, J. W. J. Chem. Phys. 1994, 100, 3422-3428.

4. “Aluminum Monochloride Excited States Observed by Resonance Enhanced Multiphoton Ionization Spectroscopy.” Dearden, D. V.; Johnson, R, D., III; Hudgens, J. W. J. Chem. Phys. 1993, 99, 7521-7528.

3. “Detection and Characterization of Gas-Phase GaCl Using Resonance Enhanced Multiphoton Ionization.” Dearden, D. V.; Johnson, R. D., III; Hudgens, J. W. J. Chem. Phys. 1992, 97, 8880-8885.

2. “Spectroscopic and ab Initio Studies of Difluoromethyl Radicals and Cations.” Dearden, D.V.; Hudgens, J. W.; Johnson, R. D. III; Tsai, B. P.; Kafafi, S. A. J. Phys. Chem. 1992, 96,585-594.

1. “New Rydberg States of Aluminum Monofluoride Observed by Resonance-Enhanced Multiphoton Ionization Spectroscopy.” Dearden, D. V.; Johnson, R. D., III; Hudgens, J. W. J. Phys. Chem. 1991, 95, 4291-4296.

Graduate Research

6. “Transition Metal Ion Mediated C-H and C-C Bond Activation of Alkanes: Dynamical Coupling Between Entrance and Exit Channel Transition States.” van Koppen, P. A. M.; Brodbelt-Lustig, J.; Bowers, M. T.; Dearden, D. V.; Beauchamp, J. L.; Fisher, E. R.; Armentrout, P. B. J. Am. Chem. Soc. 1991, 113, 2359-2369.

5. “Kinetic Energy Release Distributions as a Probe of Ligation Effects on Potential Energy Surfaces in Organometallic Reactions. The Reversible Dehydrogenation of Cycloalkenes by Fe+.” Dearden, D. V.; Beauchamp, J. L.; van Koppen, P. A. M.; Bowers, M. T. J. Am. Chem. Soc. 1990, 112, 9372-9378.

4. “Organometallic Reaction Energetics from Product Kinetic Energy Release Distributions.” van Koppen, P. A. M.; Bowers, M. T.; Beauchamp, J. L.; Dearden, D. V. In Bonding Energetics in Organometallic Compounds; Marks, T. J., Ed.; American Chemical Society: Washington, D.C. 1990; pp. 34-54

3. “C-H Bond Activation as the Initial Step in the Co+-Mediated Demethanation of Propane: The Critical Role of Angular Momentum at the Rate-Limiting Transition State.” van Koppen, P. A. M.; Brodbelt-Lustig, J.; Bowers, M. T.; Dearden, D. V.; Beauchamp, J. L.; Fisher, E. R.; Armentrout, P. B. J. Am. Chem. Soc. 1990, 112, 5663 5665.

2. “Fundamental Studies of the Energetics and Dynamics of Ligand Dissociation and Exchange Processes at Transition Metal Centers in the Gas Phase: Mn(CO)x+, x = 1 - 6.” Dearden, D. V.; Kirchner, N. J.; van Koppen, P. A. M.; Hayashibara, K.; Bowers, M. T.; Beauchamp, J. L. J. Am. Chem. Soc. 1989, 111, 2401-2409

1. “Ionization Energetics and Unimolecular Isomerization and Decomposition Pathways of Gas Phase Pentyl, Hexyl, and Heptyl Radicals by Photoelectron Spectroscopy.” Dearden, D. V.; Beauchamp, J. L. J. Phys. Chem. 1985, 89, 5359-5365.

Undergraduate Research

4. “Cation Selectivity in a Toluene Emulsion Membrane System.” Izatt, R. M.; Dearden, D. V.; Witt, E. R.; McBride, D. W.; Christensen, J. J. Solvent Extraction and Ion Exchange 1984, 2, 459-477.

3. “Facilitated Transport from Ternary Cation Mixtures Through Water-Chloroform-Water Membrane Systems Containing Macrocyclic Ligands.” Izatt, R. M.; Lamb, J. D.; Dearden, D. V.; Brown, P. R.; McBride, D. W.; Christensen, J. J. J. Membrane Sci. 1984, 20, 273-284.

2. “Metal Separations Using Emulsion Liquid Membranes.” Izatt, R. M.; Dearden, D. V.; McBride, D. W.; Oscarson, J. L.; Lamb, J. D.; Christensen, J. J. Sep. Sci. Technol. 1983, 18, 1113-1129.

1. “Cation Fluxes from Binary Ag+- Mn+ Mixtures in a H2O - CHCl3- H2O Liquid Membrane System Containing a Series of Macrocyclic Ligand Carriers.” Izatt, R. M.; Dearden, D. V.; Brown, P. R.; Bradshaw, J. S.; Lamb, J. D.; Christensen, J. J. J. Am. Chem. Soc. 1983, 105, 1785-1790.

Education

BS, Brigham Young University (1983)
Ph.D., California Institute of Technology (1989)
NRC Postdoctoral Fellow, U.S. National Institute of Standards and Technology (1989-1990)
NSF Young Investigator (1993-1998)